M-NITROBENZENESULFONIC ACID, NA SALT
3-Nitrobenzenesulfonic Acid Sodium Salt
CAS: 127-68-4
Molecular Formula: C6H4NNaO5S
M-NITROBENZENESULFONIC ACID, NA SALT - Names and Identifiers
| Name | 3-Nitrobenzenesulfonic Acid Sodium Salt |
| Synonyms | RESIST SALT 3-nitrobenzenesulfonate 3-nitrobenzenesulfonic acid SODIUM M-NITROBENZENESULFONATE sodium 3-nitrobenzenesulfonate SODIUM 3-NITROBENZENESULFONATE Sodium 3-nitrobenzenesulphonate M-NITROBENZENESULFONIC ACID, NA SALT 3-Nitrobenzenesulfonic Acid Sodium Salt M-NITROBENZENESULFONIC ACID SODIUM SALT 3-NITROBENZENESULFONIC ACID SODIUM SALT NITROBENZENESULFONIC(M-) ACID, SODIUM SALT |
| CAS | 127-68-4 |
| EINECS | 204-857-3 |
| InChI | InChI=1/C6H5NO5S/c8-7(9)5-2-1-3-6(4-5)13(10,11)12/h1-4H,(H,10,11,12)/p-1 |
| InChIKey | LJRGBERXYNQPJI-UHFFFAOYSA-M |
M-NITROBENZENESULFONIC ACID, NA SALT - Physico-chemical Properties
| Molecular Formula | C6H4NNaO5S |
| Molar Mass | 225.15 |
| Density | 0.45 g/cm3 (20 °C) |
| Melting Point | 350 °C |
| Boling Point | 217.5°C |
| Flash Point | 100°C |
| Water Solubility | 200 g/L (20 ºC) |
| Solubility | Easily soluble in water, soluble in ethanol, insoluble in ether. Decomposition by chop in aqueous solution. Solubility in water: 200G/L (20°C). |
| Vapor Presure | 10.3Pa at 25℃ |
| Appearance | Bright yellow crystal |
| Color | Light yellow |
| BRN | 3639982 |
| pKa | 0[at 20 ℃] |
| PH | 8 (50g/l, H2O, 23℃) |
| Storage Condition | Store below +30°C. |
| Stability | Stable. Hygroscopic. Incompatible with strong oxidizing agents. |
| Sensitive | Hygroscopic |
| MDL | MFCD00007490 |
| Physical and Chemical Properties | Light yellow powder. melting point 70 °c soluble in water and ethanol. |
| Use | It is a dye intermediate, used as a vat dye, sulfur dye anti-dyeing agent and dye color protection agent, and can be used as a Marine rust inhibitor and electroplating nickel removal agent |
M-NITROBENZENESULFONIC ACID, NA SALT - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | R36 - Irritating to the eyes R43 - May cause sensitization by skin contact |
| Safety Description | S24 - Avoid contact with skin. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 - Wear suitable gloves. |
| WGK Germany | 1 |
| RTECS | DB7195000 |
| TSCA | Yes |
| HS Code | 29049085 |
| Toxicity | LD50 orally in Rabbit: > 2000 mg/kg |
M-NITROBENZENESULFONIC ACID, NA SALT - Upstream Downstream Industry
| Raw Materials | Benzene Sodium carbonate Sulfuric acid Sulfuric acid Nitrobenzene Nitric acid |
| Downstream Products | 3-Hydroxy-N,N-diethylaniline |
M-NITROBENZENESULFONIC ACID, NA SALT - Nature
Open Data Verified Data
white crystals, melting point 70 °c, deliquescent in air. Soluble in water and ethanol, and gradually decomposed in aqueous solution.
Last Update：2024-01-02 23:10:35
M-NITROBENZENESULFONIC ACID, NA SALT - Preparation Method
Open Data Verified Data
using benzene as raw material, benzene sulfonic acid was prepared by sulfonation of fuming sulfuric acid, and then nitrated with nitric acid to produce m-nitrobenzenesulfonic acid, then neutralized with lime milk to obtain calcium M-nitrobenzenesulfonate, and then replaced with pure alkali, product M-nitrobenzenesulfonate.
Last Update：2022-01-01 10:55:27
M-NITROBENZENESULFONIC ACID, NA SALT - Use
Open Data Verified Data
It can be used as a dye intermediate, an anti-dyeing agent for sulfur dyes and a color forming and protecting agent for dyes, and can be used as a rust remover for ships and a nickel removing agent for electroplating, and can also be used to prepare vanillin and the like. It can also be used as a chemical reagent in chemical analysis.
Last Update：2022-01-01 10:55:27
M-NITROBENZENESULFONIC ACID, NA SALT - Safety
Open Data Verified Data
- toxic, its toxicity is slightly less than the toxicity of M-nitrobenzene. Rat oral LD50 looomg/kg. Due to this product is easy to moisture, so the inhalation of this product dust is easy to hydrolysis with the physiological cycle of discharge from the body to reduce toxicity. The production site should be strengthened ventilation, the operator should wear protective equipment, the equipment is required to be sealed, to prevent the inhalation of this product dust.
- the use of plastic bag jacket woven bag packaging, each bag weight 25kg, storage and transport when moisture, waterproof, fire, sunscreen. According to the provisions of toxic substances storage and transportation.
Last Update：2022-01-01 10:55:28
M-NITROBENZENESULFONIC ACID, NA SALT - Reference Information
| LogP | -2.61 at 25℃ |
| EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
| use | used as a catalyst, also used in organic synthesis, dye industry, etc. this product is a mild oxidant, which can protect the color light when printing or padding, dyeing and steaming of the fabric. when cooking and mercerizing the fabric, it should be attached to stop the knife wire and mask to offset the effect of reducing substances, it can also be used as an oxidant in dye synthesis. this product is used as anti-dyeing agent for vat dyes, sulfur dyes and color protection agent for dyes, rust remover for ships and nickel removal agent for electroplating, and is also an intermediate for dyes and vanillin. It is a dye intermediate, used as an anti-dye agent for vat dyes, sulfide dyes and a color protective agent for dyes, and can be used as a ship's rust inhibitor and electroplating nickel removal agent Sodium m-nitrobenzene sulfonate is used as a vat dye, an anti-dye agent for sulfide dyes and a color protective agent for dyes, a ship's rust removal agent and an electroplating nickel removal agent, and an intermediate for dyes and vanillin. |
| production method | industrial production can be obtained by sulfonation and neutralization of nitrobenzene. Raw material consumption quota: benzene (98%)400 kg/t, sulfuric acid (98%)550 kg/t, nitric acid (98%)390 kg/t, liquid alkali (30%)500 kg/t, fuming sulfuric acid (containing SO 320%)410 kg/t, lime milk 550 kg/t, soda ash (95%)30 kg/t. in enamel kettle, 350 parts of fuming sulfuric acid are added first, the temperature of the kettle is controlled to 0~5 ℃, nitrobenzene is slowly added under stirring, 132 parts of nitrobenzene are added within 1h, then the temperature of the kettle is raised to 100 ℃, and the temperature is kept for 2h. Sampling to measure the sulfonation end point (drop 1~2 drops of materials into 10ml test tube filled with clear water, and no turbidity proves to reach the end point). After the sulfonation reaction is completed, it is cooled, slowly added into ice water, and 2,000 parts of salt are added in about 3 hours. After salting out for several hours, it is left to stand overnight, sucked and filtered, and pressed to dry to obtain the intermediate m-nitrobenzene sulfonic acid. Put m-nitrobenzene sulfonic acid into 500 parts of hot water, boil and dissolve. Remove a small amount of sulfone. Add 50 parts of soda ash to neutralize and then add activated carbon to decolorize, filter while hot, and cool and crystallize the filtrate. The filter cake is washed with a small amount of water and dried below 50 ℃ to obtain the finished product. |
| spontaneous combustion temperature | 355°C |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
Last Update：2024-04-09 20:49:11
Supplier List
Spot supply
Product Name: 3-Nitrobenzenesulfonic Acid Sodium Salt Request for quotationCAS: 127-68-4
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3787852685
Spot supply
Product Name: 3-Nitrobenzenesulfonic Acid Sodium Salt Request for quotationCAS: 127-68-4
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Product Name: Landiolol Impurity 60 Sodium Salt Request for quotation
Tel: 0714-3999186
Email: 2853786052@qq.com
Mobile: 86+15671228036
QQ: 2853786052
Wechat: 15671228036
Tel: 0714-3999186
Email: 2853786052@qq.com
Mobile: 86+15671228036
QQ: 2853786052
Wechat: 15671228036
Multiple Specifications
Product Name: Sodium 3-nitrobenzenesulphonate Request for quotationCAS: 127-68-4
Tel: +86 19849939632
Email: 2470479589@qq.com
Mobile: +86 19849939632
QQ: 2470479589
Wechat: +86 19849939632
Product Name: 3-Nitrobenzenesulfonic Acid Sodium Salt Request for quotation
CAS: 127-68-4
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Wechat: 17505222756
CAS: 127-68-4
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Wechat: 17505222756
Spot supply
Product Name: Sodium 3-nitrobenzenesulphonate Request for quotationCAS: 127-68-4
Tel: 15335994747
Email: 3521670276@qq.com
Mobile: 15335994747
QQ: 3521670276
Wechat: A2020071098
Product Name: 3-Nitrobenzenesulfonic Acid Sodium Salt Request for quotation
CAS: 127-68-4
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
CAS: 127-68-4
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Spot supply
Product Name: 3-Nitrobenzene sulfonic acid sodium salt Visit Supplier Webpage Request for quotationCAS: 127-68-4
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
Spot supply
Product Name: 3-Nitrobenzenesulfonic Acid Sodium Salt Request for quotationCAS: 127-68-4
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3787852685
Spot supply
Product Name: 3-Nitrobenzenesulfonic Acid Sodium Salt Request for quotationCAS: 127-68-4
Tel: +86-17551318830
Email: r@reformchem.com
Mobile: +86-17551318830
QQ: 3785839865
Product Name: Landiolol Impurity 60 Sodium Salt Request for quotation
Tel: 0714-3999186
Email: 2853786052@qq.com
Mobile: 86+15671228036
QQ: 2853786052
Wechat: 15671228036
Tel: 0714-3999186
Email: 2853786052@qq.com
Mobile: 86+15671228036
QQ: 2853786052
Wechat: 15671228036
Multiple Specifications
Product Name: Sodium 3-nitrobenzenesulphonate Request for quotationCAS: 127-68-4
Tel: +86 19849939632
Email: 2470479589@qq.com
Mobile: +86 19849939632
QQ: 2470479589
Wechat: +86 19849939632
Product Name: 3-Nitrobenzenesulfonic Acid Sodium Salt Request for quotation
CAS: 127-68-4
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Wechat: 17505222756
CAS: 127-68-4
Tel: 17505222756
Email: pules.cn@gmail.com
Mobile: +86-17551318830
Wechat: 17505222756
Spot supply
Product Name: Sodium 3-nitrobenzenesulphonate Request for quotationCAS: 127-68-4
Tel: 15335994747
Email: 3521670276@qq.com
Mobile: 15335994747
QQ: 3521670276
Wechat: A2020071098
Product Name: 3-Nitrobenzenesulfonic Acid Sodium Salt Request for quotation
CAS: 127-68-4
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
CAS: 127-68-4
Tel: 0086-551-65418684
Email: sales@tnjchem.com
info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Spot supply
Product Name: 3-Nitrobenzene sulfonic acid sodium salt Visit Supplier Webpage Request for quotationCAS: 127-68-4
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409
Wechat: 18301782025
View History
Raw Materials for M-NITROBENZENESULFONIC ACID, NA SALT
Downstream Products for M-NITROBENZENESULFONIC ACID, NA SALT